In collaboration with Rice University · Mesoscale Materials Science Group

Solving Dendrites

An interactive guide to why lithium-ion batteries fail, what grows inside them, and how researchers are working to stop it.

01The basics

How a lithium-ion battery works

Every lithium-ion battery is a sandwich: two electrodes, a liquid electrolyte between them, and a thin separator that keeps them apart. Energy is stored by moving lithium ions from one side to the other and back again.

Lithium ion (Li⁺) Electron (e⁻)
e⁻ →Your deviceelectrolyteelectrolyteAnode (−)SeparatorCathode (+)graphite on copper foilporous polymer filmmetal oxide on aluminum foil

Discharging: powering your device

Lithium ions leave the graphite, cross the electrolyte and separator, and settle into the cathode. Electrons can't take that route, so they travel through the outside circuit instead. That flow of electrons is the current that runs your phone, laptop, or e-bike.

Anode (−)

Usually graphite: stacked sheets of carbon. Lithium tucks in between the sheets when the battery is charged.

Cathode (+)

A lithium metal oxide such as NMC or LFP. It takes lithium back in as the battery powers your device.

Electrolyte

A lithium salt dissolved in liquid solvent. Ions can travel through it but electrons can't, and in most cells it's flammable.

Separator

A porous plastic film thinner than a human hair. Ions pass through it, but it keeps the two electrodes from touching.

Where things go wrong: in a healthy cell, lithium slips neatly between the graphite sheets every time it charges. When it doesn't, it builds up on the anode's surface instead, and that buildup is how dendrites begin.

02The problem

What are dendrites?

Every time a lithium battery charges, lithium ions move to the negative electrode. Ideally they tuck neatly inside it. Under the wrong conditions, the lithium instead grows as thin, branching metal filaments called dendrites.

Short circuits

Dendrites pierce the protective internal separator to cause fatal battery short circuits.

Accelerated capacity loss

Dendrites permanently trap lithium ions to drastically reduce the battery lifespan.

Thermal runaway and fires

Dendrite short circuits spark intense heat that triggers explosive battery fires.

How a dendrite actually forms

Play through the five stages, or tap any step to jump to it.

ANODESEPARATORCATHODE

Stage 1 of 5 · not to scale

Watch dendrites grow atom by atom

Our kinetic Monte Carlo simulator lets you change the conditions and see what the lithium does.

Open the simulator

03Why it matters

Where this shows up in daily life

Lithium-ion batteries are in nearly everything that holds a charge: phones, laptops, power tools, power banks, e-bikes and scooters, hearing aids, electric vehicles, and grid-scale storage. When they fail, the costs add up fast.

E-bikes & scooters

Consumer electronics

Electric vehicles

Aviation

Cost of the Samsung Galaxy Note7 recall
$0B+

Source: Samsung via AP — ≈$5.3B total

Cost of the Chevy Bolt EV battery recall
$0B

Source: GM / LG — ~$1.9B reimbursed, ~$2B total

Deaths from lithium-ion battery fires in New York City in 2023
0

Source: NYC Mayor's Office / FDNY

Burn time of the 2021 Victorian Big Battery fire
0 hrs

Source: Technical investigation — burned out in ~6 hrs

04Best practices

Keeping dendrites at bay

A few everyday habits keep lithium plating slow, even, and manageable.

Charge at Moderate Rates

Fast charging pushes ions in faster than they can settle evenly, encouraging dendrite growth.

Try it on your phone: turn on Optimized Battery Charging (iPhone) or Adaptive Charging / Battery Protection (Android) in your battery settings. Your phone learns your routine and eases off the last stretch of charging instead of rushing to 100%.

Avoid Charging in the Cold

Charging below freezing slows ion diffusion, making uneven, dendrite-prone plating more likely.

Don't Overcharge

Sitting at 100% for long periods stresses the electrode and encourages filament growth.

Keep Temperatures Moderate

Excess heat during charging accelerates degradation and uneven lithium deposition.

Try it: how risky is this charge?

Pick the conditions and see how they stack up.

Temperature
Charging speed
Charge to

Plating risk

Elevated

  • Save fast charging for when you need it. A standard charger is gentler day to day.
  • Turn on Optimized / Adaptive Charging so the phone holds at 80% until you need it.

An illustration of which conditions matter, not a lab measurement.

05Your battery

Personal advice for the batteries you own

Tell us what you use and how you charge it, and get advice that fits. Then see how much capacity your own battery has left.

Check your device

What to do for the batteries you own

Your phone charges every day, so small habits add up.

Phones are charged more often than almost anything else you own. Heat and long stretches at 100% are what wear the battery fastest.

The one habit

Let the software help

Built-in charge limits keep the battery out of the highest charge levels, where lithium is most likely to plate.

Do

  • Turn on Optimized or Adaptive Charging so the phone waits near 80% until you need it
  • Use the charger that came with it, or one from a reputable brand
  • Take off a thick case if the phone gets hot while charging

Avoid

  • Charge it under a pillow, on a bed, or in a hot car
  • Keep using it if the screen or back starts lifting away from the frame

06Chemistry

The anode decides how easily dendrites grow

Dendrites grow on the anode, the negative electrode that lithium flows into while charging. What it's made of changes how likely lithium is to pile up as metal, and it trades off against how much energy the battery holds and how long it lasts.

Highlight
PropertyLithium metalGraphiteSiliconLithium titanate (LTO)
Dendrite growth riskVery highIntermediateModerateVery low
Typical energy density

~350–500 Wh/kg

Prototype cells; highest possible

~200–300 Wh/kg

Today's standard

~300–400+ Wh/kg

About 10× graphite's capacity

~60–100 Wh/kg

Lowest of the four

Thermal stability

Low

Very reactive, melts at ~180 °C

Moderate

Its protective surface film breaks down when overheated

Moderate

Similar to graphite

Very high

Highly resistant to thermal runaway

Typical cycle life

~100–500

Still in development

~1,000–3,000

Depends on the cathode

~500–1,000

More silicon means fewer cycles

~5,000–20,000+

Barely changes size as it charges

Why the dendrite riskNothing holds the lithium, so it plates bare metal onto bare metal every charge.Stores lithium very close to the voltage where lithium metal plates out.Swells up to ~3× as it charges; the cracking makes deposition uneven.Works at a voltage far above where lithium metal can form.
Where you'll find itNext-generation and solid-state research cellsMost phones, laptops, and EVs todayBlended into graphite in some newer phones and EVsElectric buses, grid storage, very fast-charging systems

Energy density is for a full cell, and all values are typical ranges. Real numbers depend on the cathode, cell design, and how the battery is used.

07Detection

How researchers actually see dendrites

Dendrites are microscopic and hidden inside a sealed cell, so seeing them takes X-rays, electron beams, and specially built cells.

08Engineering

What's being done about it

None of these fully solve dendrite growth on their own. Most products combine several.

Solid Electrolytes

A rigid electrolyte can physically resist penetration in a way liquid electrolytes can't.

Artificial SEI Coatings

Engineered protective layers promote a smoother, more uniform flow of lithium ions.

Pulse Charging

Alternating charge and rest pulses give ions time to settle evenly instead of piling up.

Smart Battery Management

ML-driven battery management systems adjust current in real time based on temperature and impedance.

09Reference

Glossary

The vocabulary you'll run into throughout this site.

9 terms found

Anode
The electrode that hosts lithium during charge (graphite or metal); where dendrites typically nucleate.
Cathode
The positive electrode that lithium ions travel toward during discharge, and away from during charging.
Electrolyte
The liquid, gel, or solid medium that carries lithium ions between the anode and cathode.
Separator
A thin, porous membrane that physically keeps the electrodes apart while still letting ions pass through.
SEI Layer
Solid Electrolyte Interphase — a thin passivation film that forms on the anode from electrolyte breakdown, shaping how evenly lithium plates.
Thermal Runaway
A self-accelerating chain reaction where heat from an internal failure triggers more heat, often ending in fire or explosion.
Dendrite
A branching, needle-like filament of metallic lithium that forms from uneven plating during charging.
Cycle Life
The number of charge/discharge cycles a battery can undergo before its usable capacity drops significantly.
Energy Density
How much energy a battery stores per unit of weight or volume — the main driver of range and runtime.

Check yourself

How well do you know your dendrites?

Six quick questions on everything above.

Question 1 / 6

What primarily causes lithium dendrites to form during charging?

0 of 6 answered, 0 correct